Merck, 374008-1G, 2,2,2-Trifluoroethanethiol

Name: 2,2,2-Trifluoroethanethiol
Brand: Merck
SKU: 374008-1G

Size:1 g, 95%

Available Catalog Numbers

374008-10G 374008-1G

Catalog Number: 374008-1G

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Category

Alcohols

Pack Size1 g

TagsChemistry & Biochemicals Building Blocks Organic Building Blocks

CollectionsMerck / Sigma‑Aldrich Organic & Fluorinated Building Blocks Merck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

General description
2,2,2-Trifluoroethanethiol is a fluorinated thiol. The microwave spectrum of 2,2,2-trifluoroethanethiol, and its deuterated species, CF₃CH₂SD has been studied. The gas phase acidity and basicity of 2,2,2-trifluoroethanethiol (TFET) has been investigated by Fourier transform ion cyclotron resonance spectroscopy. Reaction of 2,2,2-trifluoroethanethiol on Mo(110) surface was studied using temperature-programmed section, Auger electron and infrared spectroscopies.
2,2,2-Trifluoroethanethiol is basic in nature and forms charge transfer complexes with molecular iodine.
Application

Advancements in Peptide Synthesis: A novel synthesis of β-thiol phenylalanine showcases the use of 2,2,2-Trifluoroethanethiol in facilitating one-pot ligation-desulfurization chemistry. This technique is pivotal for developing new peptide-based pharmaceuticals, enhancing both the efficiency and versatility of peptide synthesis (Malins et al., 2015).

Specifications

General

NACRES	NA.22
PubChem Substance ID	24863272
UNSPSC Code	12352100
MDL number	MFCD00134386
InChI	1S/C2H3F3S/c3-2(4,5)1-6/h6H,1H2
SMILES string	FC(F)(F)CS
InChI key	RYRLLAOLJVDVNN-UHFFFAOYSA-N
vapor pressure	7.85 psi ( 20 °C)
assay	95%
form	liquid
refractive index	n20/D 1.352 (lit.)
bp	34-35 °C (lit.)
density	1.305 g/mL at 25 °C (lit.)
functional group	fluoro
Quality Level	200

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