Thermo Fisher, B21166.14, 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Name: 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals
Brand: Thermo Fisher
SKU: B21166.14

Quantity: 25 g, Unit Size: Each, 1, 1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for pa

Catalog Number: B21166.14

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Category

Amines

Pack Size25 g

TagsChemicals Organic compounds Unclassified Organic Compounds

CollectionsThermo Fisher Chemicals Collection — Analytical Solvents, Reagents & CoAs Thermo Fisher Clinical Analyzers & Instruments for Diagnostic Labs Thermo Fisher General Lab Supplies for Daily Workflows — Nalgene, Nunc, Samco & Matrix

Description

Quantity: 25 g
Unit Size: Each
Applications1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.SolubilitySoluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.NotesAir sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Specifications

General

Storage Note 1
Assay Percent Range	0.97
CAS	12150-46-8
Chemical Name or Material	1,1'-Bis(diphenylphosphino)ferrocene
DOT Information	Hazard Class: 6.1; Packaging Group: III
Formula Weight	554.4
Health Hazard 1	H301-H312-H332
Health Hazard 2	<b>GHS H Statement</b><br />H315-H319-H335<br />Causes skin irritation.<br />Causes serious eye irritation.<br />May cause respiratory irritation.
Health Hazard 3	P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c
IUPAC Name	λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
InChI Key	KZPYGQFFRCFCPP-UHFFFAOYSA-N
MDL Number	MFCD00001422
Melting Point	∼182°C (decomposition)
Molecular Formula	C34H28FeP2
Recommended Storage	Keep cold; Store under Argon
SMILES	[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
Sensitivity	Air sensitive
Solubility Information	Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.

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Thermo Fisher, B21166.14, 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

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