Thermo Fisher, L15141.06, [Bis(trifluoroacetoxy)iodo]benzene, 97%

Name: [Bis(trifluoroacetoxy)iodo]benzene, 97%
Brand: Thermo Fisher
SKU: L15141.06

Quantity: 5 g, Unit Size: Each, [Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1, 3, 4-oxadiazoles by the oxidation of N-acylhydrazo

Catalog Number: L15141.06

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Category

Amines

TagsChemicals Organic compounds Benzenoids Benzene and substituted derivatives Iodobenzenes

CollectionsThermo Fisher Chemicals Collection — Analytical Solvents, Reagents & CoAs Thermo Fisher Clinical Analyzers & Instruments for Diagnostic Labs Thermo Fisher General Lab Supplies for Daily Workflows — Nalgene, Nunc, Samco & Matrix

Description

Quantity: 5 g
Unit Size: Each
Applications[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.SolubilityInsoluble in water.NotesLight and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases.

Specifications

General

Beilstein	764767
CAS	2712-78-9
Chemical Name or Material	[Bis(trifluoroacetoxy)iodo]benzene
EINECS Number	220-308-0
Formula Weight	430.04
Health Hazard 1	H315-H319-H335
Health Hazard 2	<b>GHS H Statement</b><br />H315-H319-H335<br /> Causes skin irritation.<br />Causes serious eye irritation.<br />May cause respiratory irritation.
Health Hazard 3	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
IUPAC Name	[phenyl-(2,2,2-trifluoroacetyl)oxy-
InChI Key	PEZNEXFPRSOYPL-UHFFFAOYSA-N
MDL Number	MFCD00009672
Melting Point	122°C to 125°C
Molecular Formula	C10H5F6IO4
PubChem CID	102317
Recommended Storage	Keep cold
SMILES	C1=CC=C(C=C1)I(OC(=O)C(F)(F)F)OC(=O)C(F)(F)F
Sensitivity	Light and moisture sensitive
Solubility Information	Insoluble in water.
Synonym	bis trifluoroacetoxy iodo benzene
TSCA	No
Molecular Weight (g/mol)	430.041

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