Merck, 179701-100ML, Triethylborane solution

Name: Triethylborane solution
Brand: Merck
SKU: 179701-100ML

Size:100 mL, Triethylboron, 1.0 M in THF

Available Catalog Numbers

179701-100ML 179701-800ML

Catalog Number: 179701-100ML

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Category

Chelating Agents

Pack Size100 mL

TagsChemistry & Biochemicals Chemical Synthesis Reducing Agents

CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

Application
Catalyst for:
Allylation of aldehydes
Decarboxylative C-C bond cleavage reactions
Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
Regioselective hydroxyalkylation of unsaturated oxime ethers

Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes

Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential
Triethylborane is used as a catalyst for:
Allylation of aldehydes
Decarboxylative C-C bond cleavage reactions
Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
Regioselective hydroxyalkylation of unsaturated oxime ethers

It can be employed as a reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes and for the synthesis of tetramethylammonium trialkylphenylborate salts.

Specifications

General

NACRES	NA.22
PubChem Substance ID	24850826
eCl@ss	38120201
UNSPSC Code	12352001
MDL number	MFCD00009022
Beilstein/REAXYS Number	1731462
InChI	1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
SMILES string	CCB(CC)CC
InChI key	LALRXNPLTWZJIJ-UHFFFAOYSA-N
form	liquid
reaction suitability	reagent type: reductant
concentration	1.0 M in THF
density	0.865 g/mL at 25 °C
Quality Level	100

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