Merck, 190306-100ML, Diisobutylaluminum hydride solution

Name: Diisobutylaluminum hydride solution
Brand: Merck
SKU: 190306-100ML

Size:100 mL, DIBAL, DIBAL-H, 1.0 M in hexanes

Available Catalog Numbers

190306-100ML 190306-4X100ML 190306-800ML

Catalog Number: 190306-100ML

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Category

Chelating Agents

Pack Size100 mL

TagsChemistry & Biochemicals Chemical Synthesis Reducing Agents

CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

General description
Diisobutylaluminum hydride reducing agent is commonly used for the reduction of an ester to aldehyde.
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp₂Cl from ZrCp₂Cl₂ and DIBAL-H.
Diisobutylaluminum hydride solution (1.0 M in hexanes) can be used in the synthesis of potassium diisobutyl-t-butoxyaluminum hydride (PDBBA), a novel reducing agent for the chemoselective conversion of esters in the presence of nitriles. The DIBAL-triethylamine complex can reduce α-oxoketene dithioacetal to the saturated ketone.

Specifications

General

UNSPSC Code	12352001
NACRES	NA.22
PubChem Substance ID	24851429
MDL number	MFCD00008928
Beilstein/REAXYS Number	4123663
InChI	1S/2C4H9.Al.H/c21-4(2)3;;/h24H,1H2,2-3H3;;
SMILES string	CC(C)C[AlH]CC(C)C
InChI key	AZWXAPCAJCYGIA-UHFFFAOYSA-N
form	liquid
reaction suitability	reagent type: reductant
concentration	1.0 M in hexanes
density	0.701 g/mL at 25 °C
Quality Level	200

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