Merck, 214949-100ML, Diisobutylaluminum hydride solution

Name: Diisobutylaluminum hydride solution
Brand: Merck
SKU: 214949-100ML

Size:100 mL, DIBAL, DIBAL-H, 1.0 M in cyclohexane

Available Catalog Numbers

214949-100ML 214949-800ML

Catalog Number: 214949-100ML

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Category

Chelating Agents

Pack Size100 mL

TagsChemistry & Biochemicals Chemical Synthesis Reducing Agents

CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

Application
Diisobutylaluminum hydride solution (DIBAL-H) can be used as a reducing agent in the:
Hydrogenation of ester modified hydroxyl-terminated polybutadiene (HTPB) using cobalt catalyst.
Synthesis of primary 6-OH alcohols by regioselective ring opening of 4,6-benzylidene acetals of hexopyranosides using triphenylcarbenium tetrafluoroborate as a catalyst.
Conversion of an ester to alcohol.

Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

Specifications

General

NACRES	NA.22
PubChem Substance ID	24852856
eCl@ss	38120609
UNSPSC Code	12352001
MDL number	MFCD00008928
Beilstein/REAXYS Number	4123663
InChI	1S/2C4H9.Al.H/c21-4(2)3;;/h24H,1H2,2-3H3;;
SMILES string	CC(C)C[AlH]CC(C)C
InChI key	AZWXAPCAJCYGIA-UHFFFAOYSA-N
form	liquid
reaction suitability	reagent type: reductant
concentration	1.0 M in cyclohexane
density	0.781 g/mL at 25 °C
Quality Level	100

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