Merck, 287717-10G, Borane-ammonia complex

General description
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Ammonia borane, also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane takes place in the temperature range of 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donation from a Lewis base (NH₃) to a Lewis acid (BH₃). It shows a B-N bond distance of 1.564 Å.
Application
Borazane acts as a mild, efficient, and stereoselective reducing agent for aldehydes and ketones in protic or nonprotic media.It can be used as a storage medium for release of hydrogenBorazane is popularly used as an ammonia borane (AB) source for the formation of hexagonal boron nitride monolayers which are used as a substrate for graphene growth.