Merck, 338370-1G, Pentamethylcyclopentadienylrhodium(III) chloride dimer

Name: Pentamethylcyclopentadienylrhodium(III) chloride dimer
Brand: Merck
SKU: 338370-1G

Size:1 g, 1, 3-Cyclopentadiene, 1, 2, 3, 4, 5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, 97%

Available Catalog Numbers

338370-1G 338370-250MG

Catalog Number: 338370-1G

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Category

Enzyme Catalysts

Pack Size1 g

TagsCatalysts Chemistry & Biochemicals Transition Metal Catalysts

CollectionsMerck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

Application
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for:
Oxidative olefination reactions
C-C bond cleavage of secondary alcohols
Ortho C-H olefination of phenol derivatives
Oxidative annulation of pyridines
Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond
Amidation reactions
Reductive alkylation reactions

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:
Oxidative olefination reactions
C-C bond cleavage of secondary alcohols
Ortho C-H olefination of phenol derivatives
Oxidative annulation of pyridines
Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond
Amidation reactions
Reductive alkylation reactions

Specifications

General

UNSPSC Code	12161600
PubChem Substance ID	24860540
NACRES	NA.22
Web Name Suffix Override	97%, solid
MDL number	MFCD00061552
SMILES string	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChI key	QNIVKTTWBMFSBR-UHFFFAOYSA-J
assay	97%
form	solid
reaction suitability	core: rhodium

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