Merck, 391573-1G, 1-Bromopyrene

Name: 1-Bromopyrene
Brand: Merck
SKU: 391573-1G

Size:1 g, 96%

Catalog Number: 391573-1G

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Category

Alcohols

Pack Size1 g

TagsChemistry & Biochemicals Building Blocks Organic Building Blocks

CollectionsMerck / Sigma‑Aldrich Organic & Fluorinated Building Blocks Merck Cell Culture Supplements & Reagents: Complete Solutions for Research & Bioproduction Merck Roche Life Science Products for PCR, RT‑PCR & Nucleic Acid Purification

Description

General description
1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method.
Application
1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.
1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons.
It may be used in the synthesis of the following:

2-methyl-4-pyren-1-yl-but-3-yn-2-ol
1-ethynylpyrene
silsesquioxane (SSQ) based hybrid
ruthenium nanoparticles functionalized with pyrene moiety
mono- and di-pyrenyl perfluoroalkanes
oligo(1-bromopyrene)(OBrP) films
dinitropyrene-derived DNA adduct

Specifications

General

NACRES	NA.22
PubChem Substance ID	24864389
UNSPSC Code	12352100
MDL number	MFCD00015767
InChI	1S/C16H9Br/c17-14-9-7-12-5-4-10-2-1-3-11-6-8-13(14)16(12)15(10)11/h1-9H
SMILES string	Brc1ccc2ccc3cccc4ccc1c2c34
InChI key	HYGLETVERPVXOS-UHFFFAOYSA-N
assay	96%
form	powder
mp	102-105 °C (lit.)
functional group	bromo
Quality Level	100

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Merck, 391573-1G, 1-Bromopyrene

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