Thermo Fisher, B20998.14, Di-tert-butylchlorophosphine, 96%

Name: Di-tert-butylchlorophosphine, 96%
Brand: Thermo Fisher
SKU: B20998.14

Quantity: 25 g, Unit Size: Each, Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation

Catalog Number: B20998.14

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Category

Chlorides

Pack Size25 g

TagsChemicals Organic compounds Organophosphorus compounds

CollectionsThermo Fisher Chemicals Collection — Analytical Solvents, Reagents & CoAs Thermo Fisher Clinical Analyzers & Instruments for Diagnostic Labs Thermo Fisher General Lab Supplies for Daily Workflows — Nalgene, Nunc, Samco & Matrix

Description

Quantity: 25 g
Unit Size: Each
ApplicationsDi-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.SolubilityMiscible with terahydrofuran.NotesAir and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Specifications

General

CAS	13716-10-4
Chemical Name or Material	Di-tert-butylchlorophosphine
DOT Information	Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Density	0.951
Flash Point	62°C (144°F)
Formula Weight	180.66
Health Hazard 1	H227-H314-H335
Health Hazard 2	<b>GHS H Statement</b><br />H314-H318-H227<br />Causes severe skin burns and eye damage.<br />Causes serious eye damage.<br />Combustible liquid.
Health Hazard 3	P210-P235-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
IUPAC Name	ditert-butyl(chloro)phosphane
InChI Key	MCRSZLVSRGTMIH-UHFFFAOYSA-N
Linear Formula	[(CH<sub>3</sub>)<sub>3</sub>C]<sub>2</sub>PCl
MDL Number	MFCD00008815
Molecular Formula	C8H18ClP
Odor	Acrid
PubChem CID	139566
Recommended Storage	Ambient temperatures; Store under Argon
Refractive Index	1.484
SMILES	CC(C)(C)P(C(C)(C)C)Cl

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Thermo Fisher, B20998.14, Di-tert-butylchlorophosphine, 96%

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