Thermo Fisher, H27535.03, 1,3-Dimesitylimidazolium chloride, 95%

Name: 1,3-Dimesitylimidazolium chloride, 95%
Brand: Thermo Fisher
SKU: H27535.03

Quantity: 1 g, Unit Size: Each, Used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1, 3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides. This The

Catalog Number: H27535.03

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Category

Chlorides

TagsChemicals Organic compounds Organoheterocyclic compounds Azoles Imidazoles

CollectionsThermo Fisher Chemicals Collection — Analytical Solvents, Reagents & CoAs Thermo Fisher Clinical Analyzers & Instruments for Diagnostic Labs Thermo Fisher General Lab Supplies for Daily Workflows — Nalgene, Nunc, Samco & Matrix

Description

Quantity: 1 g
Unit Size: Each
ApplicationsUsed as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides.SolubilitySlightly soluble in water.NotesStore away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Specifications

General

CAS	141556-45-8
Chemical Name or Material	1,3-Dimesitylimidazolium chloride
Formula Weight	340.89
Health Hazard 1	H315-H319-H335
Health Hazard 2	<b>GHS H Statement</b><br />H315-H319-H335<br /> Causes skin irritation.<br />Causes serious eye irritation.<br />May cause respiratory irritation.
Health Hazard 3	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
IUPAC Name	1,3-bis(2,4,6-trimethylphenyl)imidazol-1-ium;chloride
InChI Key	OTOSIXGMLYKKOW-UHFFFAOYSA-M
MDL Number	MFCD02684541
Melting Point	>300°C
Molecular Formula	C21H25ClN2
PubChem CID	2734211
Recommended Storage	Ambient temperatures
SMILES	[Cl-].CC1=CC(C)=C(N2C=C[N+](=C2)C2=C(C)C=C(C)C=C2C)C(C)=C1
Solubility Information	Slightly soluble in water.
Synonym	1,3-bis 2,4,6-trimethylphenyl imidazolium chloride
TSCA	No
Molecular Weight (g/mol)	340.90
Percent Purity	96%
Quantity	1 g

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Thermo Fisher, H27535.03, 1,3-Dimesitylimidazolium chloride, 95%

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